The Unique Properties of Silicones

Author: Steve

May. 13, 2024

65

0

Tags: Chemicals

The Unique Properties of Silicones


The Unique Properties of Silicones

Heat Resistance

Silicone fluid is extremely stable against thermal oxidation. For example, the dimethyl silicone fluid DM-FLUID is virtually unchanged when exposed to temperatures up to 150°C in air. Methylphenyl silicone fluid exhibits even better heat resistance than dimethyl silicone fluid and can be used for long durations in environments reaching 250°C.

Read more Kinetic viscosity change of DM-FLUID-100cs and DM-FLUID-1,000cs
Heating loss of DM-FLUID-100cs and DM-FLUID-1,000cs

Low-Temperature Resistance

Silicone fluid has excellent low-temperature resistance. DM-FLUID remains fluid even at -50°C. Methylphenyl silicone fluid was specially developed for low-temperature applications, so it remains fluid even in environments of -65°C. Since temperature has little effect on viscosity, these products are ideal for applications in cold regions.

Viscosity Stability

Silicone fluid shows little change in viscosity due to changes in temperature. It is thus ideal for use as instrument oil in instruments used in airplanes, automobiles, and trains, and for other applications that make use of silicone fluid's viscous properties. Low-viscosity (10 mm2/s and below) products aside, DM-FLUID offers the advantage of less temperature-dependent viscosity change than common mineral and synthetic oils or other silicone fluids.

Thermal Conductivity

The thermal conductivity of dimethyl silicone fluid is lower than that of common organic compounds (nearly the same as that of benzene and toluene) and is roughly 25% that of water. Although thermal conductivity increases with higher viscosities, it becomes nearly constant at viscosities above 100 mm2/s. The thermal conductivity of DM-FLUID is 2.4-3.5x10-4 cal/cm·sec·°C at viscosities below 20 mm2/s, and roughly 3.7-3.8x10-4 cal/cm·sec·°C at viscosities over 50 mm2/s.

Specific Heat

The specific heat of silicone fluid varies somewhat depending on viscosity, but is generally about one-third that of water. The values are comparable to common organic compounds that have low specific heat. The specific heat of DM-FLUID is 0.39-0.47 cal/g·°C for viscosities below 20 mm2/s, and approximately 0.36 cal/g·°C at viscosities over 100 mm2/s.

Chemical Stability

Silicone fluid is nearly chemically inert and is virtually unaffected by 10% alkaline aqueous solutions or 30% acid aqueous solutions at ambient temperatures. However, viscosity increases and gelation can occur if even trace amounts of acids or alkalis are introduced at high temperatures. Silicone fluid is almost unaffected by the presence of aluminum, stainless steel, and most other metals. However, lead, selenium, and tellurium can cause gelation. Precautions must therefore be taken during handling.

Effects of DM-FLUID-50cs on metals
Effects of DM-FLUID-100cs on solder

Corrosivity and Effects on Other Materials

Silicone fluid has no adverse effect on metals, nor on most other substances. However, it may reduce the volume and weight of some rubber and plastic compounds due to extraction of the plasticizers when subjected to high temperatures. This tendency is especially strong for low-viscosity fluids. Particular care must be exercised when silicone fluid comes into contact with rubber sealing materials.

Effects of DM-FLUID-100cs on various plastics
Effects of DM-FLUID-100cs on various rubbers

Surface Tension

The surface tension of silicone fluid is much lower than that of water or common synthetic oils. Silicone fluids spread easily over the surfaces of various substances, and are thus widely used as release agents, defoamers, and ingredients for cosmetics.

Liquid Surface tension (mN/m) DM-FLUID 16 to 21 Mineral oil 29.7 Water 72

Releasability and Nonadhesiveness

The application of silicone fluid to mold surfaces prevents the adhesion of other materials, thereby enhancing mold releasability. Silicone fluids are widely used as release agents because they have excellent heat resistance and do not contaminate molds or molded materials.

Defoaming properties

Added in small amounts, silicone fluid has excellent defoaming action. Silicone fluid is primarily used as a defoamer for oil-based foaming fluids.

Water Repellency

Silicone fluid also has excellent water repellency. The degree of water repellency can be represented by water contact angle, which is over 90° for DM-FLUID. An excellent and durable water-repellent coating can be obtained by applying F-9W-9 or DM-FLUID to glass, ceramic, or fiber using a bake-on process. Silicone fluid can also be used to improve the fluidity of powders and prevent coagulation.

Water contact angleWater repellency mechanism of DM-FLUID

Physiological Effects

Generally speaking, silicone fluid is physiologically inert and poses almost no risk to people or animals. Low-viscosity products excepted, DM-FLUID is nearly harmless unless ingested in large quantities. It is thus widely used as an ingredient in cosmetics.

Results of various safety tests

Resistance to Shear Stress

Silicone fluid has extremely high shear resistance, and it resists shear degradation at high speeds and high loads, meaning it has a long operating life. When synthetic or mineral oils pass through narrow gaps under pressure, shear stress destroys the oil molecules, causing a drop in viscosity. In contrast, with dimethyl silicone fluid of viscosities below 1,000 mm2/s, there is almost no change in viscosity. However, with high-viscosity products there may be an apparent drop in viscosity depending on the shear velocity. Note that this is not due to destruction of the molecules, so the viscosity returns to the initial level when the shear stress is removed. The shear resistance of silicone fluids is over 20 times greater than that of even top-quality petroleum-based oils.

DM-FLUID: apparent kinetic viscosity and shear velocity

Compressibility

Unlike mineral oil, silicone fluid exhibits extremely high compressibility and does not coagulate when pressurized. Silicone fluid has much higher compressibility than petroleum-based insulating oils or synthetic lubricants, and is thus well-suited for use as damper oil.

DM-FLUID: pressure and compressibility (25°C)
DM-FLUID-100cs: compressibility and temperature
DM-FLUID-100cs: pressure and kinetic viscosity

Solubility

Silicone fluid is highly soluble in hydrocarbon solvents such as toluene, xylene, ligroin, and mineral spirits as well as in chlorinated hydrocarbons. However, it is insoluble in ethanol, methanol, and water.
*KF-56 is soluble in ethanol.

Solubility of silicone fluids
DM-FLUID-100cs: solubility with various solvents

Lubricity

Although silicone fluid has many advantageous properties (eg. stable viscosity, high- and low-temperature resistance) that make it ideal for use as a lubricant, its poor boundary lubrication properties on steel-steel interfaces limit its use as a lubricant for such applications. However, silicone fluid does provide good lubrication for steel-bronze, steel-aluminum, steel-zinc, and wood-wood interfaces and for various combinations of plastics.

Correlation between friction pressure and kinetic friction coefficient when silicone fluid (DM-FLUID-60,000cs) is added to various resins
Correlation between friction pressure and amount of wear when DM-FLUID-10,000cs is added to engineering plastic

Radiation Resistance

In terms of radiation resistance, methylphenyl silicone fluid is superior to dimethyl silicone fluid, and the stability of radiation resistance increases proportionately with the amount of phenyl groups present in the molecules. Due to this property and its resistance to high and low temperatures, methylphenyl silicone fluid is widely used in the high-temperature parts of radiological equipment.

Silicone Fluid

Silicone Fluid

zteastsilicone

·

Follow

5 min read

·

Aug 1, 2023

--

Silicone fluids have unique properties because they are not products of petroleum or organic chemistry. They were the first, and are still the only, major class of polymers that are products of inorganic chemistry.

Zhongtian Silicone Fluid Product Series

Among the whole products series, the silicone fluid product series launched by Zhongtian as the silicone products manufacturer is also worth a look. As liquid silicone rubber manufacturers, we offer high-quality polydimethylsiloxane and the best silicone oil that can be directly used in the damp proof, insulation, damping, shock absorption, defoaming, lubrication, polishing, etc.

Polydimethylsiloxane

Soluble in benzene, toluene, ethylene, ethyl ether, partially soluble in ethanol, butanol, acetone, insoluble in cyclohexanol, paraffin oil, vegetable oil and methanol.

Silicone Fluid Properties

Generally speaking, liquid silicone oil is colorless (or light yellow), tasteless, non-toxic, non-volatile liquid. Silicone fluid has the following special properties:

· high and low-temperature resistance

Goto OSi Silicone to know more.

Additional reading:
hypophosphoric convertion - Powered by XMB 1.9.11

· electrical insulation


Hydroxypropyl Methylcellulose Excipients Manufacturers

· weather resistance

· physiological inertia and small surface tension

· no corrosion to metal

· good insulation

Due to these properties, silicone fluid enjoys excellent effect in many aspects. Among all kinds of silicone oil, methyl silicone oil is the most widely used and the most important one

Silicone Fluid Application

The application of silicone fluid is now extending to the following fields r industries:

· Nano components: microflow channel, micromixer, micro pump, microvalve, etc.

· Body filling: breast filling

· Aerospace: protective coating of surfaces

Description of Silicone Fluid

Silicone fluid usually refers to a linear polysiloxane product that remains liquid at room temperature. It is generally divided into two categories: methyl silicone fluid and modified silicone fluid. The most commonly used silicone fluid — methyl silicone fluid, also known as ordinary silicone fluid, whose organic groups are all methyl, methyl silicone fluid has good chemical stability, insulation, and good hydrophobic properties. It is made by hydrolysis of dimethyl dichlorosilane with water to make the initial condensation ring body, the ring body by cracking, distillation to make a low ring body, and then the ring body, capping agent, catalyst put together to adjust the polymerization can get a variety of different polymerization degree of the mixture, by reducing the distillation to remove the low boiling material can be made of silicone fluid.

Advantages and Disadvantages of Silicone Fluid

Advantages

(1) The viscosity and temperature performance is the best among liquid lubricants, and the viscosity changes little in wide temperature range. Its freezing point is generally less than -50℃, some are as high as -70℃, and its oil appearance and viscosity do not change when stored for a long time at low temperature, it is a base oil that can take into account high temperature, low temperature and wide temperature range.

(2) Excellent thermal oxidation stability, such as thermal decomposition temperature >300℃, small evaporation loss (150℃, 30 days, evaporation loss is only 2%), oxidation test (200℃, 72h), small changes in viscosity and acid value.

(3) excellent electrical insulation, volume resistance, etc. does not change in the range of room temperature ~ 130 ℃ (but the oil can not contain water).

(4) It is a non-toxic and low foaming, strong anti-foaming oil, can be used as antifoaming agent, etc.

(5) Excellent shear stability, has the function of absorbing vibration and preventing vibration transmission, and can be used as vibration damping fluid.

Disadvantages

(1) The lubricity of silicone oil is not good, especially for the poor lubrication of the steel friction side.

(2) The coefficient of thermal expansion of silicone oil is large (may produce overpressure problem).

(3) Large gas solubility (difficult to design gas sealing device).

(4) A certain degree of hygroscopicity (after the water content is higher than 100×10–6, the electrical performance drops sharply).

(5) Small surface tension (easy to leak from the machine).

Harm to Human Body of Silicone Fluid

Silicone fluid was used as an implant product for women’s breast enlargement. After being used for more than forty years, silicone fluid was banned in Europe and the United States in the early nineties after it was found to cause a decrease in the body’s immune function or cause cancer. At that time, the company that produced silicone gel implants in the United States was sued and lost a lot of money. In the last two years, silicone oil was again opened for use in Europe because of the discovery that the causes of cancer in women who had breast enlargement were more complex, but it is still banned in the United States.

Some silicone oil-based products can be slightly corrosive and more care should be taken during transportation and production.

Hydrogen Silicone Oil Overview

Hydrogen silicone oil, under the action of the metal catalyst, can be cross-linked at the appropriate temperature, forming a waterproof film on the surface of various substrates. Hydrogen silicone oil is widely used as a water repellent, anti-adhesive or anti-corrosion agent for fabric, fire extinguishing agent (dry powder), paper, metal, leather, wood, glass, cement, ceramics, marble, etc.

Performance and Applications of Hydrogen Silicone Oil

Hydrogen silicone oil has particularly good hydrophobicity, suitable for many occasions such as surface treatment of glass, metal, fiber, and powder. Hydrogen silicone oil can be used as a waterproofing agent for fabrics, glass, ceramics, paper, leather, metal, cement, marble, and other materials, especially for fabrics. Methyl hydrogen silicone oil emulsion and methyl hydroxyl silicone oil emulsion share can waterproof and keep the breathability of the fabric and can improve the tear strength, abrasion strength, and stain resistance of the fabric, improve the feel of the fabric and sewing performance. In addition, hydrogen silicone oil can be used as an anti-adhesive isolating agent and cross-linking agent for paper.

1. Solid silicone rubber — high temperature blending silicone rubber (HTV) to do bridging agent, anti-yellowing agent, coupling agent

2. As a cross-linking agent for liquid silicone rubber, forming Si-C bond under the catalytic effect of pt

3. Hydrogen silicone oil can be used as a water repellent agent (water repellent agent, water repellent agent) in waterproof clothing and waterproof plasterboard, under the action of metal salt catalyst, it can be cross-linked at low temperature to form a waterproof film on the surface.

4. In the MgO (electrical grade MgO) surface treatment, play an insulating role

5. Hydrogen silicone oil can be used in the textile and garment industry as a softener, water repellent, hand feeling improvement agent, lubrication of sewing line, lubrication of chemical fiber spinneret and garment pressure lining auxiliaries, etc.

Packaging and Storage of Hydrogen Silicone Oil

Hydrogen silicone oil should avoid contact with alkaline substances, acid-proof, moisture-proof, stored in a cool and dry place, the storage period of more than one year. Over the period it can be retested if it is standard qualified, hydrogen silicone oil can still be used. Hydrogen silicone oil is the non-dangerous product.

If you want to learn more, please visit our website Silicone Fluids.

Comments

0

0/2000

Guest Posts

If you are interested in sending in a Guest Blogger Submission,welcome to write for us!

Your Name:(required)

Your Email:(required)

Subject:

Your Message:(required)

0/2000